Rate-Dependent Internal Energy from Detailed-Balance Relaxation

Abstract

Thermalization in driven open quantum systems is often described as ordinary thermodynamics supplemented by additional dissipation that depends on how the system is driven. We show that when relaxation is treated consistently at the generator level within Gaussian GKLS dynamics, thermodynamics itself acquires an intrinsically dynamical state space. For a frequency-modulated harmonic oscillator coupled to a thermal bath, detailed balance selects a relaxing quadratic frame characterized by an emergent frequency $ω_I(t)$. This coordinate obeys an Onsager-type relaxation equation with a positive kinetic coefficient set by the bath coupling. As a consequence, the first law acquires an additional generalized work term, and eliminating auxiliary variables yields an internal energy of the form $E=E(ω_{I},\dotω_{I})$, or equivalently $E=E(S,\dot S)$ during thermalization. The rate dependence originates from detailed-balance relaxation rather than external driving protocols. Our results predict a measurable energy shift proportional to $\dotω_{I}/α$, providing a direct signature that thermalization enlarges thermodynamic state space.