Quantum statistical mechanical gauge invariance
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Abstract
We address gauge invariance in the statistical mechanics of quantum many-body systems. The gauge transformation acts on the position and momentum degrees of freedom and it is represented by a quantum shifting superoperator that maps quantum observables onto each other. The shifting superoperator is anti-self-adjoint and it has noncommutative Lie algebra structure. These properties induce exact equilibrium sum rules that connect locally-resolved force and hyperforce densities for any given observable. We demonstrate the integration of the framework within quantum hyperdensity functional theory and show that it generalizes naturally to nonequilibrium.